Poly[[(μ-2,2′-bipyrimidine-κ4 N 1,N 1′:N 3,N 3′)(μ-sulfato-κ2 O:O′)zinc(II)] monohydrate]
نویسندگان
چکیده
In the title compound, {[Zn(SO(4))(C(8)H(6)N(4))]·H(2)O}(n), the Zn(II) atom is in a distorted octa-hedral environment. The Zn(II) atoms are bridged by both 2,2'-bipyrimidine and sulfate ligands, thus forming a three-dimensional polymeric metal-organic solid that contains uncoordinated water mol-ecules in the inter-stitial space. O-H⋯O hydrogen bonding consolidates the crystal structure.
منابع مشابه
Poly[[tetraaquabis(μ-hydroxyacetato-κ4 O 1,O 2:O 1,O 1′)-μ2-sulfato-κ2 O:O′-dicadmium(II)] monohydrate]
The title compound, {[Cd(2)(C(2)H(3)O(3))(2)(SO(4))(H(2)O)(4)]·H(2)O}(n), was obtained unintentionally in a transmetallation reaction. The crystal structure contains a two-dimensional metal-organic framework based on Cd(II)-(μ-hydroxy-acetato-κ(4)O(1),O(2):O(1),O(1'))-Cd(II) zigzag chains joined together by bridging SO(4) anions. The resulting layers are shifted with respect to each other and a...
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The title complex, [Mn(2)(SO(4))(2)(C(8)H(6)N(4))(H(2)O)(6)], is the second monoclinic polymorph [De Munno et al. (1995 ▶). Inorg. Chem.34, 408-411; Hong et al. (1996 ▶). Polyhedron, 15, 447-452]. The asymmetric unit contains two crystallographically independent half-mol-ecules of the binuclear Mn(II) complex; an inversion centre is located at the centroid of each complex. The two Mn(II) atoms ...
متن کاملcatena-Poly[[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ4 O:O′-[(1,10-phenanthroline-κ2 N,N′)praseodymium(III)]-di-μ-phenoxyacetato-κ4 O:O′-di-μ-phenoxyacetato-κ3 O,O′:O;κ3 O:O,O′]
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متن کاملcatena-Poly[[(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzoato-κ2 O:O′]
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010